Department of Chemical Engineering.

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A review on the sustainable energy generation from the pyrolysis of coconut biomass
(Scientific African (Elsevier), 2021) Azeta Osarhiemhen; Ayeni A. O.; Agboola O.; Elehinafe Francis B.
he negative impacts of the extraction and exploration of fossil fuel on the environment and its depletion that has led to environmental degradation have encouraged researchers, stakeholders, and the government to explore alternative and renewable energy sources such as lignocellulosic biomass. Biomass pyrolysis has proven to be a viable energy conversion process over the last decade due to its low carbon footprint on the environment. Pyrolytic products that are bio-char, bio-oil, and bio-gas have several applications and contribute to our society’s industrial, commercial, and economic growth. This paper reviews the different types of pyrolytic processes using coconut biomass as a feedstock while focusing on the biomass properties that make it useful for pyrolysis and the factors affecting the process.
A Simplified Design for Biodiesel Production
(International Conference on Engineering for Sustainable World (IOP Publishing), 2021) Ayoola A. A.; Alagbe E. E.; Agboola O.; Ayeni O. A.; Adeyemi G. A.; Nnabuko D.; Makinwa
Application of mass transfer in the pulp and paper Industry􀀀 overview, processing, challenges, and prospects
(Results in Engineering (Elsevier), 2023) Odunlami Olayemi A.; Amoo Temiloluwa E.; Adisa Hassan A.; Elehinafe Francis B.; Oladimeji Temitayo E.
This study reviews the mass transfer with a focus on the challenges, benefits, processing and prospects in the pulp and paper industry with a scope limited to Kraft pulping which is the dominant pulping process worldwide. The mass transfer usually occurs in various processes that deal with reactions, separation, and heat transfer. All these aforementioned processes occur in the production of pulp and paper from their raw materials. The application of mass transfer to these processes is of great importance in setting target yields, and specifications and improving efficiency. The major processes where mass transfer principles are applied are drying, chemical washing, pulp digestion and pulp bleaching respectively. Understanding the requirements and targets of each of these processes in combination with the mass transfer principles helps in the development of models and design of equipment that operate based on the developed models in meeting the required targets. Studies have indicated that mass and energy balances cannot be done independently in meeting the required targets and equipment design. The drying and stripping of lignocellulosic components of the feed-in paper manufacture constitute a large part of the challenges faced by the industry. Drying techniques have been considered to be inefficient, and lignocellulosic by-products are known to contain toxic components. Green chemistry production processes and newer drying techniques were indicated as possible solutions. It is expected that researchers and investors would find this article useful.
CONTROL OF FOSSIL FUEL GAS OPERATING CONDITIONS ON THE PERFORMANCE OF CARBON DIOXIDE CAPTURE PROCESS
(2021) Letsholo I.; Moropeng M. L.; Mavhungu A.; Agboola O.; Fayomi O. S. I.; Moropeng R. C.
Corrosion mitigating techniques and the mechanisms: Comment
(International Conference on Engineering for Sustainable World (IOP Publishing), 2021) Ayodeji A. I.; Fayomi O.S.I.; Babaremu K. O.; Abioye P. O.; Agboola O.; Daniyan A. A.
A lasting solution is required to curb the corrosion attack because of the very destructive effect it has on engineering materials. Corrosion is a material degrading phenomenon that reduces the significant properties of metallic materials, making them less useful. This paper has been able to highlight the very suitable methods or techniques that help to mitigate the effect of corrosion on metals and other helpful engineering materials. Some of these methods are electrodeposition and protective coatings like organic coatings, inorganic coatings, and metallic coatings.
Data on the effect of Ibruprofen drug derivative on 430T1 stainless steel in acid solutions
(International Conference on Engineering for Sustainable World (IOP Publishing), 2021) Sanni O.; Fayomi O. S. I.; Popoola A. P. I.; Agboola O.
Empirical assessment of ammonia and urea concentrations in wastewater from a pharmaceutical plant: A case study
(International Conference on Energy and Sustainable Environment (IOP Conf. Series), 2021) Sanni S E.; Odigure J. O.; Agboola O.; Emetere M. E.; Okoro E. E.; Audu C.
In several ways, urea is one of the most prominent sources of fixed nitrogen due to its relative abundance in waste water treatment plants. In this study, the wastewater effluent from X-Chemical Industries was considered for hazard analysis in order to ascertain the water quality and impact at the outfall effluent of company X relative to environmental standards. The study period is for December, 2013 – February 2014. Based on the results, it was observed that at the company’s sluice gate, the desorber (primary treatment unit) did not perform optimally. Also, the variation of the parameters measured i.e. urea concentration, pH and ammonia concentrations exceeded the standards established by the World Bank, International Finance Corporation (IFC) and the National Environmental Standards and Regulations Enforcement Agency (NESREA), i.e. against the specified standard of 100 ppm, higher concentrations include December 3, 9, 11, 12, 19, 20, 21, 24, 25, 27, 28 and 29 with corresponding urea concentrations of 1457, 1970.4, 122.7, 163.2, 150.3, 171.4, 148.76, 270.78, 178, 123, 101.33 and 250.43 ppm respectively, whereas that of ammonia is higher than 5 ppm on December 3, 21, 24, 25, 26, 27, 28 and 29 with corresponding concentrations of 8.4, 9.69, 8.13, 9.45, 12.5, 6.98, 22.95 and 9.95 respectively, whereas, it was lowest on other days. It was also observed that the treated waste water advancing the creek (jetty) close to the plant, will have environmental consequences on marine lives such as marine micro-flora as well as fishes.
ENHANCEMENT OF FINGERPRINT TEMPLATE PROTECTION AND PRIVACY PRESERVATION USING FULLY HOMOMORPHIC ENCRYPTION
(Covenant University Ota, 2025-03) ITUH NICOL IGNATIUS; Covenant University Dissertation
The transition from conventional or token-based passwords to biometric technologies because of the advantageous characteristics of biometrics traits is increasing daily. Nowadays, biometric technologies are utilised in applications such as border control, e-banking, e-health, etc. Biometric traits comprise biological traits (iris, face, fingerprint, etc) and behavioural traits (keystroke, signature, voice, etc). In contrast to other biometric traits, the fingerprint is the most utilised in most applications. Despite the advantages, biometric technologies have their drawbacks. The biometric data of an individual is unique since no two people have the same biometrics, and compromising this biometric data could have devastating results. This issue was addressed using the implementation of the Paillier cryptosystem, a partial homomorphic encryption scheme which only involves addition operations. This implementation suffers drawbacks when faced with complex computations such as the multiplication of two ciphertexts and faces ciphertext noise growth due to these complex computations. Thus, a need for fully homomorphic encryption which handles complex computation and manages noise growth through several techniques. This research work is aimed at enhancing fingerprint template protection and privacy preservation using fully homomorphic encryption. The proposed system was developed utilising the Brakerski/Fan-Vercauteren fully homomorphic encryption scheme implemented using the OpenFHE-Python library. The system was evaluated using the Neurotechnology CrossMatch dataset according to performance metrics including Accuracy, Genuine Acceptance Rate (GAR) and Equal Error Rate (EER). Results indicated that the Neurotechnology CrossMatch dataset achieved an accuracy of 84%, GAR of 84%, and EER of 16%. Therefore, the implementation of fully homomorphic encryption in biometrics achieves adequate accuracy despite both the encryption and decryption processes, thereby safeguarding the template, and preserving the user’s privacy.
Fabrication and Potential Applications of Nanoporous Membranes for Separation Processes
(Environmental Nanotechnology Volume 5 (Springer, Cham), 2021-07-05) Agboola Oluranti; Popoola Patricia; Sadiku Rotimi; Sanni Samuel Eshorame; Babatunde Damilola Elizabeth; Ayoola Ayodeji; Abatan Olubunmi Grace
Innovative membrane processes are considered a very important segment of controllable separation processes, such as water treatment, gas separation and organic purification. One of the challenges in membrane technology is the challenge of selecting and fabricating membrane material for excellent selectivity and good permeability for selected particle sizes. The utmost operational challenge perturbing the performance of membrane technology is membrane fouling which occur as a result of insoluble materials covering the membrane surface, leading to a reduction in water quality. Other factors perturbing the performance of membrane technology are energy usage and greenhouse emission. Furthermore, the necessity to react to climate change is another major challenge for membrane technology. An excellent membrane should have high stiffness in order to withstand high pressures applied, large surface area and micro- or nanopore structures for excellent selectivity and good permeability for selected particle sizes. The transport of ions and fluid at molecular level, controlled at the nanometer-scale using membranes provide substantial capacity for high selectivity and high fluxes. The potential applications of nanoporous membranes are strongly subjected to the chemical and physical properties of a membrane material. The effective pores size, porosity, uniformity, thickness, surface chemistry and morphology also have influence on membrane separation performance. We reviewed the fabrication and potential applications of nanoporous membranes for separation processes, operational challenge, energy usage, greenhouse emission and effect of climate change. Thus, the major points, include: (1) fabrication methods of nanoporous membranes for excellent selectivity and good permeability for selected particle sizes, (2) Theoretical modeling and simulations of nanoporous membranes, (3) potential applications of nanoporous membranes, (4) the recent discovery of novel nanoporous membrane structures aimed at overcoming the challenge of fouling, (5) the challenge of energy usage, (6) addressing climate change as a contributing factor to the challenges of water treatment industry and membrane technology.
Gasific: A Python Tool for Biomass Gasification Process
(Advanced Manufacturing in Biological, Petroleum, and Nanotechnology Processing, 2022-04-04) Oladokun O.; Nyakuma B.; Luing W. S.; Oladimeji E.; Abatan O.; Ayeni A. O.; Agboola O.; Ayoola A. A.; Ojewunmi M. O.; Efeovbokhan V. E.
Biomass gasification and the production of syngas are important in the production of biohydrogen, a green fuel and an energy carrier for the fuel cell. The tool for the prediction of biohydrogen production from any biomass should be readily available to determine the viability of such biomass for gasification. The software implementing a robust gasification model is complex, proprietary, and expensive. In order to solve this problem, we developed Gasific, a software module for simple, free, and accurate biomass gasification product gas prediction. Gasific, implemented biomass gasification, stoichiometric equilibrium models, in Python and runs on a variety of platforms. We discussed the application of Gasific on biomass wastes, namely, Imperata cylindrica; the simulation shows good performance in predicting the gas composition product of gasification. The developed software and the code can be modified and applied to other scientific models and transform the models into software applications.
Influence of Organic Composite Material for Coating Application: A Review
(4th International Conference on Science and Sustainable Development (IOP Conf. Series), 2020) Adejumo O. A.; Fayomi O. S. I.
Composite materials have been used to coat products and substrates in different industries like Aerospace industry, Automobile industry;welding industry etc. The aim of this review is to describe the impacts and the effects of composite materials on coating applications in different industries. The first application mentioned was in the Aeronautic Industry, where powder (a composite material) is used to coat substrates. It has been studied and widely accepted as one of the most environmental friendly, economically beneficial and functional coating material. New types of powder coating are being developed to improve the aesthetic designs of Aeronautic and Automotive industries products. The second application was in the welding industry and its impacts on the electrode tool life was studied. The tool life is improved by 71% when TiC composite is used to coat the electrode.
Influence of synthetic carbon grade on the monomeric constitution of polyhydroxyalkanoate produced by Bacillus cereus AAR-1
(2024) Akinwumi A. R.; Nwinyi O. C.; Ayeni A. O.; Mohan S. Venkata
Three synthetic sucrose samples with varying manufacturing purity levels were selected as carbon substrates to synthesize diverse polyhydroxyalkanoates (PHAs) using a wild-type Bacillus cereus AAR-1. Comparative analyses of the extracted biopolymers were characterized using Fourier-transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (1H and 13C NMR), gas chromatography-mass spectrometry (GC-MS), Thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), CHNS/O elemental analysis, and X-ray diffraction (XRD). The biopolymers identified include Poly(3-hydroxytetradecanoate) (P3HTD), Poly(3-hydroxybutyrate-co-2-hydroxytetradecanoate) [P(3HB-co-2HTD)], and Poly(3-hydroxybutyrate) (P3HB). The carbon content of the biopolymers ranged from 39-53%, with no nitrogen element detected. The thermal decomposition temperature of [P(3HB-co-2HTD)] was 279 °C, surpassing the corresponding values for the other two biopolymers. Notably, the homopolymer P3HTD exhibited an increased melting temperature of 172.4 °C and a reduced crystallinity percentage (Xc %= 20%), crucial properties for bioplastics and medical sector applications. The results suggest that different carbon purity grades influenced homopolymer accumulated in Bacillus cereus AAR-1.
Microbial desalination cell technique - A review
(South African Journal of Chemical Engineering (Elsevier), 2023) Odunlami Olayemi A.; Vershima Denen A.; Tagbo Chukwudi V.; Ogunlade Stephen; Nkongho Sonia
Saltwater desalination has become a highly demanded technique for the production of clean water. As a result of the growing population of the world, the demand for healthy water for consumption and other human activities has grown, over the years. Some Industries also require water for some of their operational processes. Two major types of desalination techniques exist and they include thermal desalination and membrane desalination. Several methods have been employed to control the salt content of water, and they include Reverse Osmosis (RO), Electro-Dialysis (ED), Membrane Distillation (MO), Multi-Stage Flash (MSF) process, Multi-Effect Distillation (MED), and vapor-compression distillation (VC). Microbial fuel cell (MFC) technology is a new way to treat wastewater and it serves the purpose of power generation. It involves the use of microorganisms in the anodic chamber of a fuel cell to break down matter, thus releasing electrons to the anode that goes to the cathode (in the cathodic department). This creates a potential difference across the electric circuit. Microbial desalination cell (MDC) technology utilizes this method to remove salt from saltwater and generate electricity. It comprises three compartments, namely: anodic chamber, desalination chamber, and cathodic chamber. This study focused on MDCs and their various configurations of it. It also identified various ways to advance the technology. MDCs are excellent in salt removal from saltwater and electricity generation and can be scaled up for large-scale industrial processes.
Modelling and simulation of the volume flow of NH3, K2CO3 and for the Carbon dioxide absorption from coal
(2021) Nkhwashu M. I.; Moropeng M. L.; Agboola O.; Mavhungu A.,; Moropeng R. C.; Fayomi O. S. I.
Overview on Advancement of Sustainable Heterogeneous Catalysts for the Production of Biodiesel
(Bioenergy and Biochemical Processing Technologies, 2022-07) Efeovbokhan Vincent; Makinwa Tolu; Agboola Oluranti; Oladokun Olagoke
Biodiesel has comparable properties to diesel fuel; hence, it becomes a promising substitute to diesel fuel. The development of exceedingly effective biocatalyst is a key prerequisite for the production of biofuels, most especially biodiesel. Heterogeneous catalysts are regarded to be very prospective for transesterification process in biodiesel production owing to their numerous advantages, which include separation of catalyst from reaction mixture with ease, separation from reaction mixture with ease, regeneration, decreased corrosion, decreased cost and environmental friendliness. Heterogeneous catalysts can substitute homogeneous catalysts in situations that limit their efficiency. Hence, synthesized sustainable catalysts are required for increasing process performance, reduction in energy cost and production of cleaner products like ultralow sulphur biodiesel. Here, we gave a brief review on the advancement in sustainable heterogeneous catalysts for biodiesel production.
Performance of mixed matrix nanofiltration membranes in wastewater treatment: A review
(International Conference on Engineering for Sustainable World (IOP Publishing), 2021) Agboola O.; Fayomi O.S.I.; Oni B.A.; Ayeni A.O.; Sadiku E.R.; Popoola A.P.I.; Moropeng I.; Adegbola S.T.; Daramola D.
Water covered close to 70% of the Earth’s surface; however, it is a struggle to access 3% of it as freshwater, suitable for human intake. The shortage of water has become a global issue due to climate change, pollution and the demand of growing freshwater. The fabrication of high performance and antifouling nanofiltration membranes are of utmost importance as a result of their capability of treating contaminated water and to also regulate the quality of freshwater. However, there is need for improvement in the fabrication of membrane using different nanofillers to produce mixed matrix membranes (MMMs). Mixed matrix nanofiltration membranes with nanofillers were reviewed for different applications
Review on coal-fired power plants from post-combustion CO2 process and challenges
(TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES21Gr, 2022-05) Agboola O.; Moropeng M. L.; Fayomi O. S. I.; Oyebanji J. A.; Oluwasegun K. M
The capturing of CO2 from power plant flue gases offers unique chance to alleviate the emissions of coal-fired power plants to the environment. The fraction of CO2 captured and the increased production of CO2 that results from loss in the whole efficiency of power plants are determinant factors for the net emissions reduction to the atmosphere via carbon dioxide capture storage. Post-combustion capture is of great interest as it is easy to implement as to existing power plants. The use of post combustion capture in power plant was reviewed. The challenges of post combustion process were reviewed with possible solutions.
Review on the impact of heavy metals from industrial wastewater effluent and removal technologies
(REVIEW ARTICLEVolume 10, Issue 23, 2024-12) Oladimeji T. E.; Oyedemi M.; Emetere M. E.; Agboola O.; Adeoye J. B.; Odunlami Olayemi A.
The incidence of water pollution in developing countries is high due to the lack of regulatory policies and laws that protect water bodies from anthropogenic activities and industrial wastewater. Industrial wastewater contains significant amounts of heavy metals that are detrimental to human health, aquatic organisms, and the ecosystem. The focus of this review was to evaluate the sources and treatment methods of wastewater, with an emphasis on technologies, advantages, disadvantages, and innovation. It was observed that conventional methods of wastewater treatment (such as flotation, coagulation/flocculation, and adsorption) had shown promising results but posed certain limitations, such as the generation of high volumes of sludge, relatively low removal rates, inefficiency in treating low metal concentrations, and sensitivity to varying pH. Recent technologies like nanotechnology, photocatalysis, and electrochemical coagulation have significant advantages over conventional methods for removing heavy metals, including higher removal rates, improved energy efficiency, and greater selectivity for specific contaminants. However, the high costs associated with these advanced methods remain a major drawback. Therefore, we recommend that future developments in wastewater treatment technology focus on reducing both costs and waste generation.
Role of Biomaterials in Automation
(International Conference on Energy and Sustainable Environment (IOP Publishing), 2021) Fayomi O. S. I.; Adedeji A. A.; Agboola O.; Ajala M. O.; Bolu C. A.; Banjo S. O.; Udoye N. E.
Technology in its real sense is in an advanced state to an extent that automation is the present-day mode of operating machinery and equipment. This technique of operating or controlling a process using a highly automatic means via electronic devices thereby reducing the human interface to a minimum, if not rather than eliminating it completely. Transformation of the global workforce has already begun through automation with innovations of robotics, artificial intelligence remote connectivity, additive manufacturing and medical innovations employing the automated means of delivering or administering drugs and performing surgery on patients. In the present day, various forms of automation are increasingly taking over the place of human thereby, putting a threat to supplant it. The role of biomaterials in automation is the main objective in this discuss. The study revealed that metals play a major role in biomaterials due to its excellent thermal conductivity and mechanical properties.
Safety and Environmental Aspects of Cellulose Nanoparticles
(Cellulose Nanoparticles: Chemistry and Fundamentals, 2021-06-01) Fasiku Victoria Oluwaseun; Agboola Oluranti; Owonubi Shesan John; Revaprasadu Neerish; Sadiku E. R.
Nanoparticles made from cellulose are increasingly gaining attention in several fields for diverse applications, which can be attributed to their excellent properties. The physical, chemical, and mechanical properties of cellulosic nanomaterials are being studied to investigate their application in areas such as drug delivery, wound dressing, artificial tissues, and others. However, the safety and environmental aspects of cellulose nanoparticles (CNPs) are yet to be fully understood and established. The ambiguity surrounding their environmental health and safety remains a serious concern to the standards community. This chapter, therefore, provides information about the types of cellulose nanoparticles, and their various properties and the characterization techniques employed to provide useful information about their properties. It further proceeds to focus on the safety and environmental issues associated with cellulose nanoparticles and the handling practices which can be implemented to ensure maximum safety. This includes various safety techniques that have been developed as precautionary measures against the release and exposure of cellulose nanoparticles into the environment.